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The Journal of Adhesive Dentistry
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J Adhes Dent 15 (2013), No. 5     15. Oct. 2013
J Adhes Dent 15 (2013), No. 5  (15.10.2013)

Page 453-459, doi:10.3290/j.jad.a29537, PubMed:23560261


Polymerization Kinetics of Dual-curing Adhesive Systems when Used Solely or in Conjunction with Chemically-cured Resin Cement
Kim, Young Kyung / Chun, Ju-Na / Kwon, Pyung Cheol / Kim, Kyo-Han / Kwon, Tae-Yub
Purpose: To investigate the chemical polymerization kinetics of commercial dual-curing adhesive systems when used solely or in conjunction with chemically-curing resin cement.
Materials and Methods: Four adhesive systems comprising simplified-step adhesives and activators (Prime&Bond NT with Self Cure Activator, Excite DSC, AQ Bond Plus, All-Bond SE) were used. The pH values of the adhesives and adhesive/activator blends were measured. Differential scanning calorimetry (DSC) was used to investigate the extent of the chemical polymerization of the adhesives when used alone or directly intermixed with a chemically-cured resin cement (C&B Cement) for 60 min (n = 5). The data derived from the DSC analysis were statistically compared using one-way ANOVA and the Games-Howell post-hoc test (α = 0.05).
Results: All the adhesives were highly acidic; when they were blended with the respective activators, their pH values increased. Neither the adhesive/activator blends nor the adhesive alone/cement mixtures showed any detectable heat generation. The Prime&Bond NT/activator showed delayed heat generation only when intermixed with the catalyst/base paste. The other three adhesive systems produced similar exotherms when intermixed with the catalyst paste alone or with the catalyst/base paste (p > 0.05), but at significantly different maximum rates of polymerization (p < 0.05). Significantly shorter induction periods resulted when AQ Bond Plus and All- Bond SE were intermixed with the catalyst/base paste rather than with the catalyst paste alone (p = 0.004).
Conclusion: The chemical polymerization occurring at the adhesive system/resin cement interface appears highly dependent on the adhesive system used and may be considerably delayed.

Keywords: activator, adhesive, polymerization, resin cement
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